Product ID:ETHYLENE GLYCOL (REGULAR)
MSDS Date:07/01/1993
FSC:6850
NIIN:00-664-1399
MSDS Number: BYRRR

VAN WATERS AND ROGERS INC

6100 CARILLON POINT
KIRKLAND, WA 98033
US

Emergency Phone: 206-889-3400

Info Phone: 206-889-3400

Cage: 0STM5

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

ETHYLENE GLYCOL (SARA 313) (CERCLA)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: >99%

ACGIH TLV: C 50 PPM,VAPOR; 9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:ORAL DL50 RATS 6000-13000MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE SLIGHT
TRANSIENT(TEMP)IRRIT.CORNEAL INJURY UNLIKELY.VAP/MIST IRRIT.
SKIN:ESSENTIALLY NON-IRRIT. SKIN ABSORPTION:REPEATED EXPO TO LG
QUANT MAY RESULT IN ABSORPTION OF HARMFUL AMTS. INGEST :SINGLE DOSE
ORAL TOXICITY MODERATE.EXCESSIVE EXPO MAY CAUSE CNS
EFFECTS,CARDIO-PULM EFFECTS,KIDNEY FAILURE.(SUPPLEMENT)
Explanation of Carcinogenicity:PER MSDS:DID NOT CAUSE CANCER IN
LONG-TERM ANIMAL STUDIES.
Effects of Overexposure:EXCESSIVE EXPO IRRIT TO UPPER RESP TRACT.EXPO
BY INHAL/SKIN PRIMARY ROUTES OF OCCUPATIONAL EXPO HAVE
MINIMAL/ESSENTIALLY NO EFFECT ON FETUS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:IRRIGATE IMMED W/WATER FOR @LEAST 5MINS.SKIN:WASH OFF IN
FLOWING WATER/SHOWER.INGEST:INDUCE VOMIT IMMED AS DIRECTED BY MED
PERSON.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.INHAL:REMOVE TO
FRESH AIR. CONSULT PHYSICIAN.NOTE TO PHYSICIAN:EARLY ADM OF ETHANOL
MAY COUNTER TOXIC EFFECTS-METABOLIC ACIDOSIS & RENAL
DMG.HEMODIALYSIS OR PERITONEAL DIALYSIS HAVE BEEN BENEFITIAL.TREAT
BSED ON DR TO RESPONSES

Flash Point Method:SCC
Flash Point:247F,119C
Lower Limits:3.2
Upper Limits:N/DETERMINED
Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR POSITIVE-PRESSURE, SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE EXPECTED UNDER NORMAL STORAGE/HNDLG
CONDITIONS(I.E. AMBIENT TEMPS).HOWEVER ETHYLENE GLYCOL OR SOLUTIONS
OF ETHYLENE GLYCOL & WATER CAN FORM FLAMM (SUPPLEM)

Spill Release Procedures:AVOID ENTRY INTO SEWERS/NATURAL WATERS.SMALL
SPILLS:SOAK UP W/ABSORBENT MATL.LARGE SPILLS:DIKE/PUMP INTO
SUITABLE CNTNRS FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID INGEST.PRACTICE REASONABLE
CAUTION/PERSONAL CLEANLINESS.AVOID SKIN/EYE CONTACT.
Other Precautions:TRACE QUANT OF ETHYLENE OXIDE MAY BE PRESENT IN
PROD.WHILE THESE QUANT COULD ACCUMULATE IN HEADSPACE AREA OF
STORAGE/TRANSP VESSELS THEY'RE NOT EXPECTED TO CREATE CONDITION
RESULTING IN IN CONCEN >0.5 PPM(TWA)IN BREATHZONE.(OSHA 1.0PPM)

Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BEL EXPO
GUIDELINE.WHEN RESP PROTECTION IS REQUIRED FOR CERTAIN OPERATIONS
USE APPROVED AIR-PURIFYING RESPIRATOR.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT FOR MOST
CONDITIONS.LOCAL EXHAU VENTI MAY BE NECESSARY FOR SOME OPERATIONS
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:SAF GLASSES,FULL-FC RESP FOR EYE DISCOMF
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER HANLDING.
Supplemental Safety and Health
FIRE/EXPLO HAZ:VAP W/AIR IF HEATED SUFFICIENTLY. HEALTH HAZ:AMTS
INGESTED INCIDENTAL TO INDUSTRIAL HNDLG NOT LIKELY TO CUASE
INJURY;HOWEVER INGEST OF LG AMTS COULD CAUSE SERIOUS
INJURY,DEATH.INHAL:HEA T/SPRAY/AEROSOL CONCEN MAY BE ATTAINED
SUFFICIENT TO CAUSE IRRIT/OTHER EFFECTS.

HCC:V5
Boiling Pt:B.P. Text:387F,197C
Vapor Pres:0.12 @25C
Vapor Density:2.14
Spec Gravity:1.1155
Solubility in Water:COMPLETELY MISCIBLE.
Appearance and Odor:COLORLESS LIQUID, PRACTICALLY ODORLESS.

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIAL.
Stability Condition to Avoid:WILL IGNITE IN AIR @775F.
Hazardous Decomposition Products:BURNING PRODUCES NORMAL PRODUCTS OF
COMBUSTION, SUCH AS CARBON MONOXIDE, CARBON DIOXIDE, & WATER.

Waste Disposal Methods:BURN IN APPROVED INCINERATOR IN ACCORDACNE W/ALL
LOCAL, STATE AND FEDERAL REGULATIONS, OR SALVAGE.CONTAINS CHEM SUBJ
TO SARA SEC313 TITLE III REPORTING:ETHYLENE GLYCOL.

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